Palladium circuit at Impala Platinum Limited–Refineries showing the MRT columns with a row of blue-coloured feed tanks.

MRT – Proven Technology for Processing Metals in Solutions
 
BATEMAN has entered into an agreement with IBC Advanced Technologies, Inc., USA, to establish a new company MRT AFRICA. The joint venture will market engineered process plants using IBC’s molecular-recognition technology (MRT). MRT AFRICA has an exclusive licence for Africa but will also operate outside Africa on a case-y-case basis. This combination of IBC’s processing technology and BATEMAN’s capability s engineer and project manager, brings novel solutions to the minerals and metals processing industry.

Formulated from a Nobel prize-winning concept, MRT provides rapid, selective extraction and recovery of cations and anions from process or waste streams and enables commercial metallurgical separations to enhance processes that were previously not technically and are economically feasible. In specific cases complete recovery of high purity (99,95 to 99,99 %) marketable metals is possible after a single-pass process. The technology utilises custom-designed organic crown molecules or other chemical ligands containing atoms and functional groups which selectively target specific metals. Selectivity is determined by the chemical nature of these molecules and their overall size and shape. When bonded to solidhydrophilic supports, such as silica orpolyacrylate, the ligands can be incorporated into resin beads, porous membranes or gels and contacted with the solutions to be processed.

Applications have been developed for many base metals and include the removal and refining of copper, cobalt and nickel from zinc and copper electrolytes, raffinates or bleed streams; of copper, zinc, nickel, manganese, iron and other metals from acid mine streams; and the removal of impurities such as bismuth, antimony, germanium, fluoride and chloride from copper and zinc refinery streams.

The removal of copper, cobalt and nickel in zinc purification will be piloted soon. Several industrial applications are now well-proven, for example the commercial recovery of cathode-quality copper from an acid mine-drainage stream at flow rates up to 20 000 l/min. A feature of MRT is that trace amounts of contaminants can be removed from large volumes of solution lowing at many bed volumes per minute. MRT has enhanced the commercial recovery of platinum, alladium and rhodium from spent automobile catalytic converters as a result of the improved recoveries achieved and the reduction of processing costs and metal inventories in the process. Palladium is separated and purified using MRT at Impala Platinum Limited–Refineries, Springs, RSA. Impala developed the process and BATEMAN built this plant in 1994/7 which was the first platinum group metals refinery to use this technology. The MRT system reduces the palladium processing time and costs and increases the palladium separation efficiency and recovery, while having a beneficial effect on the environment.

MRT has also been proven for the efficient treatment of high copper-gold ores, with the recovery of old followed by copper and recycling of the cyanide. It can also be used for primary gold refining and tailings dam recovery.

In another application traces of mercury are removed from concentrated sulphuric acid, a by-product of various metallurgical roasting and smelting operations. More smelters are having to produce mercury-free acid in order to meet new stringent regulations and this was not achievable with traditional ion exchange systems which are ineffective when used with high acid or relatively low mercury concentrations.

The technical and economic feasibility of industrial applications of MRT will re-evaluated for clients so that complete solutions for their metal refining and recovery needs can be offered. MRT Africa will supply commercial plants, resins and consulting services following the completion of preliminary studies. Although the initial focus will be on minerals, there are many potential applications of MRT in the chemical industry which will be developed in due course.

Kindly contact Neill Birdsey, General Manager, Small Projects,
on +27-11-899-3191 or email tawana@batemanengineering.com for more information.


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